A pressure-amplifying framework material with negative gas adsorption transitions. Very large breathing effect in the first nanoporous chromium( iii)-based solids: MIL-53 or Cr iii(OH) xH 2O y. Chemical control of structure and guest uptake by a conformationally mobile porous material. Solvent‐induced control over breathing behavior in flexible metal–organic frameworks for natural‐gas delivery. Recent advances in gas storage and separation using metal–organic frameworks. Methane storage in flexible metal–organic frameworks with intrinsic thermal management. Near-perfect CO 2/CH 4 selectivity achieved through reversible guest templating in the flexible metal–organic framework Co(bdp). Efficient separation of ethylene from acetylene/ethylene mixtures by a flexible-robust metal–organic framework.
High CO 2/N 2/O 2/CO separation in a chemically robust porous coordination polymer with low binding energy. A partially interpenetrated metal–organic framework for selective hysteretic sorption of carbon dioxide. Elucidation of flexible metal–organic frameworks: research progresses and recent developments. Stabilization of formate dehydrogenase in a metal–organic framework for bioelectrocatalytic reduction of CO 2. Practical water production from desert air. Synthesis of metal–organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. Introduction to metal–organic frameworks. Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions. The new age of MOFs and of their porous-related solids. Balancing mechanical stability and ultrahigh porosity in crystalline framework materials. Guest exchange was shown to stimulate repeatable switching transitions between distinct disorder states.
Solvent exchange stimulates the formation of distinct disordered frameworks, as demonstrated by high-resolution transmission electron microscopy and diffraction techniques. This disorder originates from the nonlinear linkers arranging the clusters in closed loops of different local symmetries that in turn propagate as complex tilings. Here we describe a porous framework DUT-8(Ni)-which consists of nickel paddle wheel clusters and carboxylate linkers-that adopts a configurationally degenerate family of disordered states in the presence of specific guests. A prerequisite for this is bistability of the host structure, which enables the framework to breathe, that is, to switch between two stability minima in response to its environment. An interesting feature of some frameworks is the ability to open their pores to a specific guest, enabling highly selective separation. The ultrahigh porosity and varied functionalities of porous metal–organic frameworks make them excellent candidates for applications that range widely from gas storage and separation to catalysis and sensing.
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